338 CHAPTER 8: Molecular Structure and Covalent Bonding Theories
TABLE 8-3 Molecular Geometry of Species with Lone Pairs (U) on the Central Atom
Regions
of High
General Electron Electronic Hybridization at Lone
Formula Density Geometry Central Atom Pairs Molecular Geometry Examples
AB 2 U 3 trigonal sp^2 1O 3 , NO 2 , SO 2
planar
AB 3 U 4 tetrahedral sp^3 1NH 3 , SO 32
AB 2 U 2 4 tetrahedral sp^3 2H 2 O, NH 2
AB 4 U 5 trigonal sp^3 d 1SF 4
bipyramidal
Angular
Trigonal
pyramidal
Angular
Seesaw