348 CHAPTER 8: Molecular Structure and Covalent Bonding Theories
(b) glycine (an amino acid)(c) nitrobenzene(d) chloroprene (used to make neoprene, a synthetic
rubber)(e) 4-penten-1-yne*57.Predict the hybridization at the numbered atoms (➀, ➁,
and so on) in the following molecules and predict the
approximate bond angles at those atoms.
(a) diethyl ether, an anesthetic
HCHHHCO H
HHH H HCC1 2HCHHHCCC H
HCCHCH ClCHHCCC HHH HHHNOOHHCOOCHN HH(b) caffeine, a stimulant in coffee and in many over-the-
counter medicinals^1(c) acetylsalicylic acid (aspirin)^1(d) nicotine^1(e) ephedrine, a nasal decongestant^1HH HHHNHCHOH
HHC H
1243CCC CHHN
H NHHHHHHHHCH 314(^25)
3
H
H
H
C
C
O
O
O C
O H
H
H
H
H
2
1
3
H
H
HH
O
O N
N
N
C
C
C
N
H H H
H
H
H
2
1
3
(^1) In these kinds of structural drawings, each intersection of lines
represents a C atom.
O
1
C
2