348 CHAPTER 8: Molecular Structure and Covalent Bonding Theories
(b) glycine (an amino acid)
(c) nitrobenzene
(d) chloroprene (used to make neoprene, a synthetic
rubber)
(e) 4-penten-1-yne
*57.Predict the hybridization at the numbered atoms (➀, ➁,
and so on) in the following molecules and predict the
approximate bond angles at those atoms.
(a) diethyl ether, an anesthetic
H
C
HH
HCO H
H
H
H H H
CC
1 2
H
C
HH
HCCC H
H
CC
H
C
H Cl
C
H
HCCC H
H
H H
HH
N
O
O
H
HC
O
O
C
H
N H
H
(b) caffeine, a stimulant in coffee and in many over-the-
counter medicinals^1
(c) acetylsalicylic acid (aspirin)^1
(d) nicotine^1
(e) ephedrine, a nasal decongestant^1
H
H H
HH
N
H
C
H
OH
H
H
C H
1
2
4
3
CC
C C
H
H
N
H N
H
H
H
HHH
H
H
CH 3
1
4
(^25)
3
H
H
H
C
C
O
O
O C
O H
H
H
H
H
2
1
3
H
H
HH
O
O N
N
N
C
C
C
N
H H H
H
H
H
2
1
3
(^1) In these kinds of structural drawings, each intersection of lines
represents a C atom.
O
1
C
2