The Foundations of Chemistry

NAMES AND FORMULAS OF SOME IONIC COMPOUNDS

During your study of chemistry you will have many occasions to refer to compounds by
name. In this section, we shall see how a few compounds should be named. More com-
prehensive rules for naming compounds are presented at the appropriate places later in
the text.
Table 2-2 includes examples of names for a few common molecular compounds. You
should learn that short list before proceeding much farther in this textbook. We shall
name many more molecular compounds as we encounter them in later chapters.

2-4

As we shall see, some metals can form

more than one kind of ion with a

positive charge. For such metals, we

specify which ion we mean with a

Roman numeral—e.g., iron(II) or

iron(III). Because zinc forms no stable

ions other than Zn^2 , we do not need

to use Roman numerals in its name.

TABLE 2-3 Formulas, Ionic Charges, and Names of Some Common Ions

Common Cations (positive ions) Common Anions (negative ions)

Formula Charge Name Formula Charge Name

Na 1  sodium F 1  fluoride

K 1  potassium Cl 1  chloride
NH 4  1  ammonium Br 1  bromide

Ag 1  silver OH 1  hydroxide
CH 3 COO 1  acetate

Mg^2  2  magnesium NO 3  1  nitrate
Ca^2  2  calcium

Zn^2  2  zinc O^2  2  oxide
Cu 1  copper(I) S^2  2  sulfide

Cu^2  2  copper(II) SO 42  2  sulfate
Fe^2  2  iron(II) SO 32  2  sulfite

CO 32  2  carbonate
Fe^3  3  iron(III)

Al^3  3  aluminum PO 43  3  phosphate

Ionic compounds (clockwise, from top):salt
(sodium chloride, NaCl), calcite (calcium
carbonate, CaCO 3 ), cobalt(II) chloride
hexahydrate, (CoCl 2 6H 2 O), fluorite
(calcium fluoride, CaF 2 ).