Modern inorganic chemistry
416 THE TRANSITION ELEMENTS Copper(l) chloride, bromide and cyanide were used by Sandmeyer to introduce a chlorine, a bromine at ...
THE TRANSITION ELEMENTS 417 calamine, to give the oxide ZnO, which is then reduced to the metal by heating with coke, or (b) by ...
418 THE TRANSITION ELEMENTS Under no conditions is hydrogen obtained from nitric acid. With the dilute acid, reduction to ammoni ...
THE TRANSITION ELEMENTS 419 rust-preventing paints. Zinc chromate is a yellow pigment. Lithopone is also used as a filler in lin ...
420 THE TRANSITION ELEMENTS character. In the hydrated salt, and in solution, species such as [Zn(H 2 O) 6 ]^2 + exist; the latt ...
THE TRANSITION ELEMENTS 421 acid, blood-red on treating with potassium thiocyanate, gives a white precipitate with hydrogen sulp ...
422 THE TRANSITION ELEMENTS The transition metals form complexes which are usually different in kind and in stability from thos ...
THE TRANSITION ELEMENTS 423 Outline how you would determine the concentration of permanganate ions in the product (practical det ...
424 THE TRANSITION ELEMENTS (b) What is the highest oxidation state that you expect vanadium to show in its compounds? (c) Which ...
14 The elements of Groups IB and MB I (COPPER), SILVER, GOLD In Mendeleefs periodic table, these three elements appeared to- get ...
Table HI SELECTED PROPERTIES OF THE ELEMENTS Cu, Ag, Au Element Cu Ag Au /tonic numlier 29 47 79 Outer electrons [Ar]M'V [Kr]4A' ...
THE ELEMENTS OF GROUPS IB AND MB 427 Silver has little tendency to formally lose more than one electron; its chemistry is theref ...
428 THE ELEMENTS OF GROUPS IB AND IIB Silver chloride is readily soluble in ammonia, the bromide less readily and the iodide onl ...
THE ELEMENTS OF GROUPS IB AND MB 429 The formation of minute specks of silver when silver bromide is exposed to light is known t ...
430 THE ELEMENTS OF GROUPS IB AND MB In the former, it gives precipitates with halides (except the fluoride), cyanides, thiocyan ...
THE ELEMENTS OF GROUPS IB AND MB 431 can, however, be attacked by certain substances, of which three may be mentioned: In the p ...
432 THE ELEMENTS OF GROUPS IB AND MB Gold(III) chloride dissolves in hydrochloric acid to form tetra- chlorauric acid, HAuCl 4. ...
Table 142 SELECTED OF THE Zn, Cd, Hg ,. A Mom n , , lonmtionmrom Heat of Momc Owter ,. , Densifv w.p. o, ,,, ,-h . roiiMs* , v / ...
434 THE ELEMENTS OF GROUPS IB AND IIB Table 14.2 shows that all three elements have remarkably low melting points and boiling po ...
THE ELEMENTS OF GROUPS IB AND (IB 435 of a cadmium(II) salt; presence of chloride ion may reduce the concentration of Cd2+(aq) s ...
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