Modern inorganic chemistry

(Axel Boer) #1
GROUPS I AND II 129
(jroup 1 contd

Element Li

Chlorides Hydrated
deliquescent


Na K

Anhydrous

Rb Cs

Heat of formation increasing

Bromides
and
iodides


Soluble in
organic
solvents

Melting point decreasing

Insoluble in organic solvents

Heat of formation increasing

Melting point decreasing

Chlorides,
bromides and
iodides


Group II

Element

Fluorides


Be

Soluble in
water

Mg

Sparingly
^olnVilp in
water

Ca Sr

Insoluble in water

Ba

Covalent
when
anhydrous.
Soluble in
organic solvents.
Hydrolysed
by water

Soluble in water

THE OXIDES AND HYDROXIDES

The white solid oxides M^O and M"O are formed by direct union
of the elements. The oxides M! 2 O and the oxides MUO of calcium
down to radium have ionic lattices and are all highly basic; they
react exothermically with water to give the hydroxides, with acids
to give salts, and with carbon dioxide to give carbonates. For
example
Na 2 O + H 2 O -» 2NaOH
BaO + CO 2 -> BaCO 3


Magnesium oxide is almost inert towards water, but dissolves in

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