Concise Physical Chemistry
c13 JWBS043-Rogers September 13, 2010 11:27 Printer Name: Yet to Come 214 COULOMETRY AND CONDUCTIVITY we are using the notation ...
c13 JWBS043-Rogers September 13, 2010 11:27 Printer Name: Yet to Come PROBLEMS AND EXAMPLES 215 for the acid. The acidity (ioniz ...
c13 JWBS043-Rogers September 13, 2010 11:27 Printer Name: Yet to Come 216 COULOMETRY AND CONDUCTIVITY be within our measurement ...
c13 JWBS043-Rogers September 13, 2010 11:27 Printer Name: Yet to Come PROBLEMS AND EXAMPLES 217 (b) Given the additional informa ...
c13 JWBS043-Rogers September 13, 2010 11:27 Printer Name: Yet to Come 218 COULOMETRY AND CONDUCTIVITY Problem 13.2 What is the c ...
c13 JWBS043-Rogers September 13, 2010 11:27 Printer Name: Yet to Come PROBLEMS AND EXAMPLES 219 (c) Find the equilibrium constan ...
c14 JWBS043-Rogers September 13, 2010 11:27 Printer Name: Yet to Come 14 ELECTROCHEMICAL CELLS Advances in electrochemistry came ...
c14 JWBS043-Rogers September 13, 2010 11:27 Printer Name: Yet to Come HALF-CELLS 221 concentration, causing Zn^2 +(aq) to go fro ...
c14 JWBS043-Rogers September 13, 2010 11:27 Printer Name: Yet to Come 222 ELECTROCHEMICAL CELLS H 2 H 2 Pt H+ FIGURE 14.1 The hy ...
c14 JWBS043-Rogers September 13, 2010 11:27 Printer Name: Yet to Come CELL DIAGRAMS 223 TABLE 14.1 A Few Selected Reduction Pote ...
c14 JWBS043-Rogers September 13, 2010 11:27 Printer Name: Yet to Come 224 ELECTROCHEMICAL CELLS This is consistent with our trea ...
c14 JWBS043-Rogers September 13, 2010 11:27 Printer Name: Yet to Come CONCENTRATION CELLS 225 or E=E◦− RT nF lnQ which is theNer ...
c14 JWBS043-Rogers September 13, 2010 11:27 Printer Name: Yet to Come 226 ELECTROCHEMICAL CELLS the electrode compartments. Ther ...
c14 JWBS043-Rogers September 13, 2010 11:27 Printer Name: Yet to Come FINDINGE◦ 227 The Nernst equation for this cell is E=E◦− R ...
c14 JWBS043-Rogers September 13, 2010 11:27 Printer Name: Yet to Come 228 ELECTROCHEMICAL CELLS m1/2 0.00 0.01 0.02 0.03 0.04 0. ...
c14 JWBS043-Rogers September 13, 2010 11:27 Printer Name: Yet to Come THE CALOMEL ELECTRODE 229 whereaAgIof the solid precipitat ...
c14 JWBS043-Rogers September 13, 2010 11:27 Printer Name: Yet to Come 230 ELECTROCHEMICAL CELLS has a Nernst equation of Ecell=E ...
c14 JWBS043-Rogers September 13, 2010 11:27 Printer Name: Yet to Come PROBLEMS AND EXAMPLES 231 Ag;AgCl electrode in the cell Pt ...
c14 JWBS043-Rogers September 13, 2010 11:27 Printer Name: Yet to Come 232 ELECTROCHEMICAL CELLS m1/2 0.0 0.1 0.2 0.3 0.4 0.5 γ± ...
c14 JWBS043-Rogers September 13, 2010 11:27 Printer Name: Yet to Come PROBLEMS AND EXAMPLES 233 compartment is 0.0100 m but the ...
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