Thermodynamics, Statistical Physics, and Quantum Mechanics

(Axel Boer) #1

4.36 Polarization of Ideal Gas (Moscow Phys-Tech)


The potentialenergy of adipole in an electric fieldEis


where the angle isbetween thedirection of the electric field (which we
choose to be along the axis) and thedirection of a the dipolemoment.
The center ofthe sphericalcoordinatesystem is placed at the center of the
dipole. Theprobability that thedirection of the dipole iswithin asolid
angle is


The totalelectricdipole moment per unitvolume of the gas is


Introducing a newvariable anddenoting we obtain


SOLUTIONS
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