Thermodynamics, Statistical Physics, and Quantum Mechanics

(Axel Boer) #1
143

yielding

Then (S.4.44.3)becomes


with


b) In order to find the conjugatemomenta we must compute the
Lagrangian


Expressing through

we may rewritethe Hamiltonian as


c) The single-diatompartition function may becomputed as follows:


THERMODYNAMICS AND STATISTICAL PHYSICS
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