Thermodynamics, Statistical Physics, and Quantum Mechanics

(Axel Boer) #1
156 SOLUTIONS

d) During adiabatic compression, the entropy is constant, so from (S.4.52.7)


and we have


e) The work done is given by the change in internal energy since the
entropy is constant:


From (S.4.52.11), we arrive at


Critical Parameters (Stony Brook)


At the critical point we have the conditions


Now, from we have


and using (S.4.52.4) and (S.4.52.7), we get


So, (S.4.52.8) becomes


4.53

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