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GENERAL INFORMATION ON NITRO COMPOUNDS 189 Explosive nitro compounds exhibit a high degree of chemical stability and undergo no ...

190 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES Z. ECKSTEIN, T. KRACZKIEWICZ, T. URBANSKI and H. WOJNOWSKA, Bull. Acad. Polon. Sci., ...

GENERAL INFORMATION ON NITRO COMPOUNDS 191 J. THIELE, Ber. 33, 670 (1900). A. I. TITOV, Usp. khim. 27, 845 (1958). P. P. SHORYG ...

CHAPTER VI AROMATIC NITRO COMPOUNDS REACTIVITY OF THE NITRO GROUP AROMATIC nitro compounds which are of course tertiary, form a ...

AROMATIC NITRO COMPOUNDS 193 A number of reactions on the mobility of the NO 2 group have been carried out by Qvist and his co-w ...

194 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES and, hence of relatively low reactivity, may also be substituted. Thus, for example, ...

AROMATIC NITRO COMPOUNDS 195 (8) According to that author, such a typical aromatic nitro compound as 4-nitro- l-naphthol (VII) w ...

196 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES at 140°C phenazine and its oxide were formed, while at 160°C phenazine only was obtai ...

AROMATIC NITRO COMPOUNDS 197 (15) (R are alkyls) The reactivity of the nitro group is also manifested by the ease of its reduc- ...

198 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES A halogen atom in the ortho or para position to the nitro group can readily undergo n ...

AROMATIC NITRO COMPOUNDS 199 Plazek [28,28b] and Plazek and Talik [28a] stated recently that the reactivity of halogens in nitro ...

200 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES amine and with OH in dioxane-water (50/50). The results suggest that the reaction wi ...

AROMATIC NITRO COMPOUNDS 201 be added relatively easily to the methyl group of trinitrotoluene, resulting in the formation of th ...

202 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES The reaction is of great practical importance and is described in detail in the appro ...

AROMATIC NITRO COMPOUNDS hydroxide resulted in the formation of potassium picrate, to the scheme: 203 presumably according (20a) ...

204 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES The reaction of the formation of product II is fast. while that of product III is slo ...

AROMATIC NITRO COMPOUNDS 205 The oxidation of nitrobenzene to o- nitrophenol (with traces of the p- isomer) when mixed with dry ...

206 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES Holleck and Perret [51] gave the following diagrammatic presentation of nucleo- phili ...

AROMATIC NITRO COMPOUNDS^207 In the case of nitro derivatives of benzene at least two nitro groups should be present on the ring ...

208 CHEMISTRY AND TECHNOLOGY OF EXPLOSIVES Thus, nitro compounds with a great number substituents, for example trinitro- mesityl ...