urbaf2

NITRO DERIVATIVES OF TOLUENE 311

TABLE 69

Hydrocarbon Molecular proportion

or amine, etc.

α− trinitrotoluene/second

component

Melting point

°C Form

anthracene 1:1 102.5

acenaphthene 1:1 112.0

phenanthrene 1:1 87.5

fluorene 1:1 85.0

naphthalene 1:1 96.5

aniline

dimethylaniline

diphenylamine

carbazoie

α− naphthylamine

&naphthylamine

benzyl-/?-naphthyhunine

dibenzyl-&naphthylamine

o-toluidine

m-toluidine

benzaldehyde phenyl-

hydrazone

1:1

1:1

2:3

1:1

1:1

1:1

1:1

1:1

1:1

1:1

2:1

83-84

• 31.0
  ~ 140.0
  141.5
  113.5
  106.5
  108.0
  53-55
  62-63

84

brown-yellow needles

straw yellow needles

red needles

violet needles

red needles

yellow needles

dark red needles

light red needles

purple needles

brick red needles

light red needles

light red needles

dark red needles

Elucidation of the constitution of α− rinitrotoluene.................

The constitution of α− trinitrotoluene has been established on the basis of the

following reactions [36]

see eqn. (16) p. 310.