urbaf2

Nitro-solvent-naphtha ....................

Hexanitrostilbene ...................

Nitro derivatives of diphenyl..............

Nitration of mixtures.................

Nitro derivatives of polymers ............

Nitropolystyrene ..................

Literature ...................

CONTENTS ix

415

415

416

417

417

418

420

CHAPTER XI. NITRO DERIVATIVES OF NAPHTHALENE

General information................................ 422

Mononitro derivatives of naphthalene ........................ 426

Dinitro derivatives of naphthalene. ......................... 427

Physical properties ............................... 428

Composition of the commercial product ..................... 429

Chemical properties...............................^430

Trinitro derivatives of naphthalene......................... 431

Chemical properties of trinitronaphthalene isomers................. 432

Structure of α− and γ somers .......................... 433

Explosive properties and application of trinitronaphthalene............. 434

Tetranitro derivatives of naphthalene........................ 434

Structure of tetranitronaphthalenes........................ 435

Thermochemical properties of nitronaphthalenes ................... 436

Side reactions in the nitration of naphthalene .................... 437

Manufacture of nitro derivatives of naphthalene ................... 438

Nitration of naphthalene to mononitronaphthalene................. 438

Nitration of naphthalene to dinitronaphthalene..................^442

Nitration of nitronaphthalene to dinitronaphthalene................^443

Nitration of nitronaphthalene to trinitronaphthalene................^445

2-Methyl-1-nitronaphthalene............................. 446

Literature ................................... 447

CHAPTER XII. NITRO DERIVATIVES OF HALOGENOBENZENES

Nitro derivatives of chlorobenzene....................
Mononitro derivatives of chlorobenzene.................
Dinitro derivatives of chlorobenzene..................
Manufacture of o- and p- hloronitrobenzenes..............
Nitration of p- hloronitrobenzene to l-chloro-2,4-dinitrobenzene.........
Nitration of chlorobenzene to chlorodinitrobenzene (Griesheim method)......
Trinitro derivatives of chlorobenzene..................
Thermochemical and explosive properties of chloronitrobenzenes.....
Nitro derivatives of p- ichlorobenzene.................
2,4,6-Trinitro derivative of 1,3,5-trichlorobenzene............
Nitro derivatives of fluorobenzene....................
Literature ..............................

CHAPTER XIII. NITRO DERIVATIVES OF PHENOL

General information..................^472
Mononitro derivatives of phenol............ 474

450

450

452

456

458

458

459

466

466

469

470

470