Thermodynamics and Chemistry
CHAPTER 11 REACTIONS AND OTHER CHEMICAL PROCESSES 11.3 MOLARREACTIONENTHALPY 321 BIOGRAPHICAL SKETCH Germain Henri Hess (1802–18 ...
CHAPTER 11 REACTIONS AND OTHER CHEMICAL PROCESSES 11.3 MOLARREACTIONENTHALPY 322 notinclude the formation of the solvent H 2 O f ...
CHAPTER 11 REACTIONS AND OTHER CHEMICAL PROCESSES 11.3 MOLARREACTIONENTHALPY 323 H. 2 ;T^0 / H. 2 ;T^00 / H. 1 ;T^0 / H. 1 ; ...
CHAPTER 11 REACTIONS AND OTHER CHEMICAL PROCESSES 11.4 ENTHALPIES OFSOLUTION ANDDILUTION 324 B(s) (A + B)(l) sol (a) A(l) (A + ...
CHAPTER 11 REACTIONS AND OTHER CHEMICAL PROCESSES 11.4 ENTHALPIES OFSOLUTION ANDDILUTION 325 solute transferred: ÅsolHD @H @s ...
CHAPTER 11 REACTIONS AND OTHER CHEMICAL PROCESSES 11.4 ENTHALPIES OFSOLUTION ANDDILUTION 326 bc a c b 0 5 10 15 20 120 100 80 ...
CHAPTER 11 REACTIONS AND OTHER CHEMICAL PROCESSES 11.4 ENTHALPIES OFSOLUTION ANDDILUTION 327 same before and after the process. ...
CHAPTER 11 REACTIONS AND OTHER CHEMICAL PROCESSES 11.4 ENTHALPIES OFSOLUTION ANDDILUTION 328 Consider a solution process at cons ...
CHAPTER 11 REACTIONS AND OTHER CHEMICAL PROCESSES 11.4 ENTHALPIES OFSOLUTION ANDDILUTION 329 ThusLAdepends on the difference bet ...
CHAPTER 11 REACTIONS AND OTHER CHEMICAL PROCESSES 11.4 ENTHALPIES OFSOLUTION ANDDILUTION 330 ÅH(sol)DsolÅHm(sol,mB) and take th ...
CHAPTER 11 REACTIONS AND OTHER CHEMICAL PROCESSES 11.4 ENTHALPIES OFSOLUTION ANDDILUTION 331 0 0.5 1.0 1.5 2.0 q mB=mol kg^1 (a) ...
CHAPTER 11 REACTIONS AND OTHER CHEMICAL PROCESSES 11.4 ENTHALPIES OFSOLUTION ANDDILUTION 332 CLis equal to the limiting slope o ...
CHAPTER 11 REACTIONS AND OTHER CHEMICAL PROCESSES 11.5 REACTIONCALORIMETRY 333 11.5 Reaction Calorimetry Reaction calorimetry is ...
CHAPTER 11 REACTIONS AND OTHER CHEMICAL PROCESSES 11.5 REACTIONCALORIMETRY 334 R.T 1 / P.T 2 / P.T 1 / H(expt) H.rxn,T 1 / H. ...
CHAPTER 11 REACTIONS AND OTHER CHEMICAL PROCESSES 11.5 REACTIONCALORIMETRY 335 system in order for the temperature to return to ...
CHAPTER 11 REACTIONS AND OTHER CHEMICAL PROCESSES 11.5 REACTIONCALORIMETRY 336 ignition wires platinum resistance thermometer sa ...
CHAPTER 11 REACTIONS AND OTHER CHEMICAL PROCESSES 11.5 REACTIONCALORIMETRY 337 R.T 1 / R.T 2 / P.T 2 / U.R/ U(expt) U.IBP;T 2 ...
CHAPTER 11 REACTIONS AND OTHER CHEMICAL PROCESSES 11.5 REACTIONCALORIMETRY 338 the temperature fromT 1 toT 2. From the first law ...
CHAPTER 11 REACTIONS AND OTHER CHEMICAL PROCESSES 11.5 REACTIONCALORIMETRY 339 HereCV(P) andCV(R) are the heat capacities at con ...
CHAPTER 11 REACTIONS AND OTHER CHEMICAL PROCESSES 11.5 REACTIONCALORIMETRY 340 Molar volumes of condensed phases are much smalle ...
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