Index
Index
Aboldfacepage number refers to a definition. A page number followed by “b” is for a
biographical sketch, one followed by “n” is for a footnote, and one followed by “p” is for a
problem.
Absolute zero, unattainability of, 161
Acid dissociation constant, 409
Activity, 269 , 408
of an electrolyte solute, 292
of a gas, 185 , 272
of an ion, 288
of a mixture constituent, 272
of a pure liquid or solid, 272
relative, 269
of a solute, 272
of a solvent, 272
of a symmetrical electrolyte, 290
Activity coefficient, 257 , 258
approach to unity, 260
of a gas, 185
from the Gibbs–Duhem equation,
264 – 265
of an ion, 287
from the Debye–Huckel theory, ̈ 294
mean ionic
from the Debye–Huckel theory, ̈ 296
of an electrolyte solute, 292
from the Nernst equation, 463
from the osmotic coefficient, 299
from solubility measurement, 391
of a symmetrical electrolyte, 289
from the osmotic coefficient, 265 – 267
of a solute
in dilute solution, 260
from gas fugacity, 261 – 264
of a solvent, 370 n
from gas fugacity, 261 – 264
stoichiometric, 293
Activity quotient, 350
Additivity rule, 229 , 233 , 237 , 242 , 289 , 291 ,
293 , 303 , 307 , 328 , 346
Adiabat, 77
Adiabatic
boundary, 28
calorimeter, 168 – 170 , 333
demagnetization, 158 , 160
flame temperature, 341
process, 51 , 57 , 95 , 128
Advancement, 314
Affinity of reaction, 342 n
Amount, 21 , 37
Amount of substance, 21 , 37 , 470
Ampere, 470
Anisotropic phase, 30 , 74
Antoine equation, 220 p
Athermal process, 304
Avogadro constant, 21 , 471
Azeotrope, 405 , 435
minimum-boiling, 435
vapor-pressure curve, 436
Azeotropic behavior, 433
Azeotropy, 435
Bar, 39
Barometric formula, 197 , 276
Barotropic effect, 33
Base units, 19 , 470
Binary mixture, 223
in equilibrium with a pure phase, 374
Binary solution, 224
Bivariant system, 199 , 419
Body, 28520