Synthetic Inorganic Chemistry

(John Hannent) #1
GENERAL QUESTIONS VI 219

GENERAL QUESTIONS VI
ELEMENTS OF GROUP III


  1. Make a table of all the elements of Group III, giving in
    succeeding columns: (1) the symbols of the elements in the order
    of their increasing atomic weights, placing the elements of the A
    Family in the left of the column, and of the B Family in the right;
    (2) the formula of the hydroxide, or hydroxides, if more than one
    is described in reference books; (3) the character of the hydroxide,
    distinguishing strongly acid, weakly acid, amphoteric, weakly
    basic, and strongly basic; (4) the formula of the chloride, or chlor-
    ides; (5) the degree of hydrolysis of the chloride, distinguishing
    complete, much, little, or none.

  2. Compare aluminum hydroxide with the hydroxides of sodium
    and magnesium, the corresponding elements in Groups I and II,
    as regards solubility and degree of ionization.

  3. Compare the thermal stability of magnesium and aluminum
    carbonates — of dry magnesium and aluminum sulphates. What
    do the facts thus cited show as to the relative basic strength of
    magnesium and aluminum oxides?

  4. Describe the successive observations that are made when
    NaOH solution is added gradually to an A1C1 3 solution until an
    excess of the base is present. Likewise describe observations
    when HC1 solution is added gradually to an Na 3 A10 3 solution
    until the acid is in excess. Write fully ionized intersecting equa-
    tions corresponding to each observation, and explain how the
    amphoteric character of aluminum hydroxide is manifested in this
    experiment.

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