Synthetic Inorganic Chemistry

(John Hannent) #1
GENERAL QUESTIONS X 319


  1. Name the simplest hydrogen compounds of nitrogen, phos-
    phorus, arsenic, and antimony. Compare the stability of these
    hydrides when heated. Compare any ability they may possess to
    unite with water to form bases, and with acids to form salts.

  2. Write the equations for the reaction of nitric acid with phos-
    phorus, arsenic, antimony, and bismuth, respectively. Describe
    the properties of the product in each case.

  3. How do the trisulphides of arsenic and antimony behave
    when treated with a solution of Na^S? With a solution of Na^S-S^?
    How does the solution obtained with sodium polysulphide behave
    when it is acidified? Give equations for all the reactions.
    What is the relation between sulpho- and oxy-acids? Show,
    for example, how sodium sulpharsenate is derived from two simple
    sulphides, and sodium arsenate from the corresponding oxides.

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