Synthetic Inorganic Chemistry

(John Hannent) #1
APPENDIX 363

holds them together. The formulas of methane, carbon tetra-
chloride, sulphate ion, perchlorate ion, are shown as follows, it
being remembered that the kernel charges are: 1 for hydrogen,
4 for carbon, 6 for oxygen, and 7 for chlorine; and that the
completed sheath of hydrogen contains but two electrons.

H:

H
C:
H

H : Cl:

Cl:
C :
Cl:

Cl:

*
: 0:
.

0:
S :
0 :

0:

*
: 0:

0 :
Cl:
0 :

0:

If one counts the positive and negative charges of these formulas it
is noted that CH 4 and CC1 4 are electrically neutral, but that the
sulphate ion has a net of 2 negative charges, S0 4 ~~, and the
perchlorate ion has a net of one negative charge, C104~.

SOLUBILITIES

A substance is classified as soluble if as much as 2 parts by
weight dissolves in 100 parts of water. There is no sharp dividing
line between soluble and insoluble, but in general a substance is
classified as insoluble if less than 1 part by weight dissolves in 100
parts of water. It is advisable to learn the following general
statements of solubilities.

SOLUBLE IN WATER


  1. All simple salts of sodium, potassium, and ammonium.

  2. Acetates and nitrates, except some basic acetates and ni-
    trates.

  3. Chlorides, except AgCl, HgCl, CuCl, PbCl 2.

  4. Sulphates, except BaSO 4 , SrSO 4 , CaSO 4 , PbSO 4.


INSOLUBLE IN WATER


  1. Oxides and hydroxides

  2. Carbonates

  3. Phosphates

  4. Sulphides and ammonium.


except those of
sodium, potassium,
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