Emulsifi cation 145eter determining the destabilization kinetics
of emulsion. Large droplets are prone to
sedimentation and coalescence, whereas
fi nely dispersed emulsions are more sensitive
to fl occulation and Ostwald ripening
(McClements 1999 ).
The bulk physicochemical and organolep-
tic properties of emulsions depend on molec-emulsion instability: creaming or sedimenta-
tion; Ostwald ripening, which is a diffusion
transport of the dispersed phase in small
droplets into larger ones; coalescence, which
is the process in which two droplets combine
to form a single droplet; and fl occulation,
which is the aggregation of droplets due to
collisions. The droplet size is the key param-
liquid +
emulsifying
egents
(caseinate)
spices +
additivesprecooked
fatty tissue
(>80°C)liver + salts +
egg whitespices +
ascorbateprecooked fatty
tissue (>80°C)liver + salt + milk
proteins + egg whiteProduction flow 1 for hot emulsion Production flow 2 for hot emulsionProtein fragmentation
+ solubilisation
T° < 7°CStructuration
T° > 35°Cfat
fragmentationstructuration 1
35°C < T° < 55°Cstructuration 2
T° > 35°Cfragmentation
+ solubilisationthermal treatment thermal treatmentabProduction flow for cold emulsionLean
fragmentationprotein
solubilisationstructuration
T° < 12°Cchilled fatty
tissues + spices
+ non-meat
ingredientsicesalt, phosphateschilled lean meatthermal treatmentFigure 7.1. a. Processing diagrams for “ cold ” emulsions. b. Processing diagrams for “ hot ” emulsions.