Emulsifi cation 145
eter determining the destabilization kinetics
of emulsion. Large droplets are prone to
sedimentation and coalescence, whereas
fi nely dispersed emulsions are more sensitive
to fl occulation and Ostwald ripening
(McClements 1999 ).
The bulk physicochemical and organolep-
tic properties of emulsions depend on molec-
emulsion instability: creaming or sedimenta-
tion; Ostwald ripening, which is a diffusion
transport of the dispersed phase in small
droplets into larger ones; coalescence, which
is the process in which two droplets combine
to form a single droplet; and fl occulation,
which is the aggregation of droplets due to
collisions. The droplet size is the key param-
liquid +
emulsifying
egents
(caseinate)
spices +
additives
precooked
fatty tissue
(>80°C)
liver + salts +
egg white
spices +
ascorbate
precooked fatty
tissue (>80°C)
liver + salt + milk
proteins + egg white
Production flow 1 for hot emulsion Production flow 2 for hot emulsion
Protein fragmentation
+ solubilisation
T° < 7°C
Structuration
T° > 35°C
fat
fragmentation
structuration 1
35°C < T° < 55°C
structuration 2
T° > 35°C
fragmentation
+ solubilisation
thermal treatment thermal treatment
a
b
Production flow for cold emulsion
Lean
fragmentation
protein
solubilisation
structuration
T° < 12°C
chilled fatty
tissues + spices
+ non-meat
ingredients
ice
salt, phosphates
chilled lean meat
thermal treatment
Figure 7.1. a. Processing diagrams for “ cold ” emulsions. b. Processing diagrams for “ hot ” emulsions.