PHYSICAL CHEMISTRY IN BRIEF

(Wang) #1
CHAP. 9: CHEMICAL KINETICS [CONTENTS] 325

Solution
The specification for the batch reactor is the same as in the Example in9.7.2. The volume of
the batch reactor is 100 cm^3.
For the flow reactors we first calculate the feed. From the material balance we have

F=

1

τ

np
cA0−cA

=

1

32. 57

250

2. 6 − 0. 1

= 3. 07 dm^3 hr−^1.

The volume of the stirred flow reactor will be calculated from (9.170)

Vr=

1

νA

F

kcA

(cA−cA0) =

1

− 1

3. 07

0. 1 · 0. 1

(0. 1 − 2 .6) = 767. 5 dm^3.

The volume of the plug flow reactor will be calculated from (9.169)

Vr=

F

k

ln

cA0
cA

=

3. 07

0. 1

ln

2. 6

0. 1

= 100dm^3.

The volumes of the batch and plug flow reactors are the same, the volume of the stirred flow
reactor is more than seven-times higher.
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