inorganic chemistry
Boggio-Pasqua, M.; Bearpark, M. J.; Robb, M. A.The Spectrum2008, 21 , Shaik, S.Phys. Chem. Chem. Phys.2010, 12 , 8706. Moens, ...
Hisaeda, Y.; Shimakoshi, H. In:“Handbook of Porphyrin Science, Vol. 10”; Eds. Kadish, K. M., Smith, K.; Guilard, R.; World Scie ...
This page intentionally left blank ...
TRANSITION METAL COMPLEXES AS SOLAR PHOTOCATALYSTS IN THE ENVIRONMENT: A SHORT REVIEW OF RECENT DEVELOPMENT ZOFIA STASICKA Facul ...
crucial roles. Mono- or mixed-metal photocatalytic cycles are stimulated, in which the complex photoreduction is accompanied by ...
which solar photoreduction is of crucial environmental relevance because it is accompanied by organic pollutant oxidative degrad ...
absorbed by a photosensitizer or photocatalyst and transferred to the substrate molecule. Due to sunlight energy that is limited ...
and is the main driving power of environmental reactivity. Among catalyzed photolysis those reactions that follow substrate abso ...
Coordination compounds are known for their photochemical properties, which may result in photodissociation, photosubstitution, p ...
responsible for their higher solubility in water at all pH values. Humic acids, being more aromatic, become insoluble when the c ...
of most dyes; the second O 2 singlet state (^1 Sg) is more difficult to reach (157 kJ mol^1 ), but is much more reactive. The^3 ...
organophosphorus pesticides ( 12 ), and irgarol 1051 (2-met- hylthio-4-terbutylamino-6-cyclopropylamino-s-triazine) ( 13 ). HS f ...
the sun, absorption or diffusion infrared radiation emitted by the terrestrial surface, as well as by increase in the albedo of ...
Aromatic, olefinic, and acetylenic hydrocarbons, but especially saturated hydrocarbons belong to persistent pollutants difficult ...
be photooxidized to S(VI) species on an aqueous suspension of Fe 2 O 3 (20,26) as well as by means of oxidants produced in natur ...
and by the reaction between NO 2 and O 3 in which the NO 3 radi- cal is formed that is a key compound in nighttime atmospheric ...
corresponds to the total number of (dþp*NO) electrons) that allows for a general classification of transition metal nitrosyls wi ...
½FeL 5 ðÞH 2 O^2 þþNO^ !½FeL 5 ðÞNO^2 þþH 2 O ð 11 Þ The overall binding constantKNOrepresenting the ratio of the rate constan ...
possible thermal- and photoinitiated precursors of nitrovasodilators and anticancer agents. Experiments in various biological sy ...
physiological temperatures and pH(54,58). In the reaction of NO with oxymyoglobin, an iron(III)–nitrato complex was identified a ...
«
11
12
13
14
15
16
17
18
19
20
»
Free download pdf