inorganic chemistry

ligand like pyridinedicarboxylate (pda). This behavior was interpreted by the reaction series: CrIIIðÞC 2 O 42 ðÞpda hi 3

! h ...

and its concentrations are too low for the existence of the dimeric Cr 2 O 72
form. Both monomeric anions absorb the near-UV pa ...

Their oxidative degradation starts from PET analogous to that shown for alcohols (Eq. 67). In the case of anionic electron donor ...

The former case is illustrated inFig. 4a, showing two alternative pathways for the redox cycles photocatalyzed by Fe(III) or Cu( ...

that control the Cu environmental speciation and thus its bio- availability and toxicity. The role of chromium compounds (Fig. 4 ...

organic matter by environmental polyoxometallates as photocatalysts may constitute alternative possibilities( 264 ). VI. Conclud ...

Environmental photosensitization processes may be stimulated not only by natural but also by anthropogenic pollutants, such as p ...

Hessler, D. P.; Frimmel, S. H.; Oliveros, E.; Braun, A. M.J. Photochem. Photobiol. B. Biol.1996, 36 , 56. Zhao, X.; Quan, X.; Z ...

Harrop, T. C.; Tonzetich, Z. J.; Reisner, E.; Lippard, S. J.J. Am. Chem. Soc.2008, 130 , 15602. Chen, Y. J.; Ku, W. C.; Feng, L ...

Stochel, G.; Brindell, M.; Macyk, W.; Stasicka, Z.; Szaciłowski, K. Bioinorganic photochemistry(1st edn.). Wiley: Chichester, 2 ...

Sarma, M.; Kalita, A.; Kumar, P.; Singh, A.; Mondal, B.J. Am. Chem. Soc.2010, 132 , 7846. McQuade, L. E.; Lippard, S. J.Inorg. ...

Kusic, H.; Koprivanac, N.; Lon, A.; Bozic, L.; Selanec, I.J. Hazard. Mater. B2006, 136 , 632. Kusic, H.; Koprivanac, N.; Horvat ...

Yu, H.; Irie, H.; Shimodaira, Y.; Hosogi, Y.; Kuroda, Y.; Miyauchi, M.; Hashimoto, K.J. Phys. Chem. C2010, 114 , 16481. Moraes, ...

Trovo, A. G.; Melo, S. A. S.; Nogueira, R. F. P.J. Photochem. Photobiol. A Chem.2008, 198 , 215. Bautitz, I. R.; Nogueira, R. F ...

Adan, C.; Martınez-Arias, A.; Malato, S.; Bahamonde, A.Appl. Catal. B: Environ.2009, 93 , 96. Mansilla, H. D.; Bravo, C.; Ferre ...

Wang, Z.; Ma, W.; Chen, C.; Zhao, J.Environ. Sci. Technol.2008, 42 , Liu, Y.; Deng, L.; Chen, Y.; Wu, F.; Denga, N.J. Hazard. ...

This page intentionally left blank ...

PHOTOCHEMICAL ACTIVATION AND SPLITTING OF H 2 O, CO 2 , AND N 2 INDUCED BY CT EXCITATION OF REDOXACTIVE METAL COMPLEXES ARND VOG ...

Keywords:Photocatalysis; Photo splitting; Solar energy utili- zation; H 2 O, CO 2 , CO 32
,N 2 ; Last Glacial Maximum. I. Intro ...

complexes are initiated by CT excitation, which in simple cases leads to a one-electron transfer between metal and ligand or ano ...