inorganic chemistry

Vogler, A.; Kunkely, H. In:“Photosensitization and Photocatalysis”; Eds. Kalyanasundaram, K.; Grätzel, M.; Kluwer Academic Publ ...

Blanchet-Boiteux, C.; Mouesca, J. -M.J. Phys. Chem. 2000, A 104, 2091 – 2097. Kunkely, H.; Vogler, A.Inorg. Chem. Commun.2001, ...

Lay, P. A.; Magnuson, R. H.; Taube, H. J.Am. Chem. Soc.1985, 107 , 2551 – 2552. Lay, P. A.; Magnuson, R. H.; Taube, H.Inorg. Ch ...

VISIBLE LIGHT PHOTOCATALYSIS BY METAL HALIDE COMPLEXES CONTAINING TITANIA AS A SEMICONDUCTOR LIGAND HORST KISCH Department of Ch ...

chlorine atom. In the case of the rhodium surface complex, the excitation is of rhodium-to-titanium charge-transfer type resulti ...

radical cation generated in the reaction step according to Eq. (4) undergoes a fast and irreversible decomposition (Eq. 6) rende ...

necessary for excitation. The positions of the upper valence band and lower conduction band edge are given as electrochemical po ...

Once formed, the primary redox products are converted in subsequent thermal reactions steps to the final compounds Ared and Dox. ...

induces a splitting of the Fermi level into quasi-Fermi levels of electrons and holes indicated as nEF andpEF, respectively. Sin ...

Since the procedure requires irradiation, different to the classical Mott–Schottky method, it is more correct to replace Efb by ...

In the following, we discuss our results on the characterization and photocatalytic properties of titania–halogenometal complexe ...

separation and IFET can be described. Detailed information is available from recent original publications (13,18– 20 ). A. PREPA ...

water no desorption occurred within 24 h of irradiation time, whereas in the presence of 0.1 M HCl desorption of [PtCl 6 ]^2  w ...

0.26 V in the case of 1%, 2%, and 4.0%H 2 [PtCl 6 ]/TH, respectively. The reproducibility of quasi-Fermi potential and photocata ...

irradiation time. These conditions should favor photodesorption (vide supra) and therefore a long-term irradiation was conducted ...

whereas the 1.1% and 4.0% surface modified counterparts after 420 min exhibited 10% and 50% degradation, respectively (Fig. 5). ...

scavenging experiments with benzoic acid and tetranitromethane, an alternative electron acceptor. The adsorbed chlorine atom is ...

1.0, 2.0, and 5.0 wt% of rhodium and 2%RhBr 3 /TH were prepared as described above for the chloroplatinate complexes. Again the ...

Both 4.0%RhCl 3 /TH and 4.0%RhBr 3 /TH did not undergo desorp- tion of the rhodium surface complex even after stirring for five ...

same intensity as the 510 nm band. It rather may originate from a rhodium-to-titanium charge-transfer transition. This is corrob ...