inorganic chemistry

F

IG

. 5.

Absorption spectra of: (a) H

TPP (full line) and H 2

TF 2

PP (dashed line); (b) H 2

TCl 2

PPethyl (full line) and 2

H

TFPBmethyl (dashed line); and (c) Zn 2

II

TPP (regular metalloporphyrin, solid line), Cu

II

TPP (hypso-type spectrum,

dashed line), and Mn

III

TPPCl in toluene (hyper-type spectrum, dotted line).