inorganic chemistry

chemistry beyond the molecules, 48
double complex salts
3D crystalline supramolecular
network, 69
precipitation, 69
tectons, 67
toluene insertion, 69
X-ray crystal structure, 68f
micelles and vesicles
biexponential decays, 63– 64
luminescence quenching, 60
metallosupramolecular
amphiphilic block
copolymers, 61
metallosurfactants, 59
ring-opening metathesis
polymerization (ROMP), 61
Ruppz complex, 62
molecular systems
crystalline assemblies, 90– 91
1D arrays, 74– 77
2D arrays, 77– 81
3D networks, 81– 89
multivalency, 49
organometallic species, 49
photoactive arrays, 49– 50
photophysics
ground and excited-state
electronic wave, 50
Ir(III) complexes, 53
octahedral coordination
geometries, 52
Os(II) complexes, 53
Pd(II) complexes, 53– 54
properties, 51
Pt(II) complexes, 53– 54
Re(I) complexes, 53
spin–orbit coupling constant,
50 – 51
Stokes-shift, 52
zero-order electronic
configurations, 50– 51
photoresponsive assemblies,
noncovalent interactions
b-cyclodextrines, 56
host–guest assemblies, 55f
hydrogen bonds, 58f
interactions, 57– 58
organic chromophores, 54– 55

vectorial unidirectional

photoinduced energy transfer

process, 56

self-assembly, 48

Doping, 415– 416

XDouble complex salts

3D crystalline supramolecular

network, 69

precipitation, 69

tectons, 67

toluene insertion, 69

X-ray crystal structure, 68f

E

Electron–hole recombination,

410 – 411

Environmental

compartments–transition

metal transport

classification, photocatalysis,

295f

complexation effects

anthropogenic chelating

agents, 299

naturalchelating ligands,

296 – 299

sacrificial electron acceptor, 295

sunlight, 293– 296

F

Fenton reaction, 317– 318

Fermi level, 402– 403

First-order kinetics, 406– 407

Förster-cycle, acid–base equilibria,

254, 254f

Franck–Condon factor, 204– 205

G

Gibbs-energy change, 399–400, 399f

H

Hydride transfer shuttles, 263– 264

J

Jablonski diagram, 7f

L

Langmuir–Hinshelwood mechanism,

407 – 410, 409f

INDEX 433