Fundamentals of Materials Science and Engineering: An Integrated Approach, 3e

GTBL042-12 GTBL042-Callister-v2 August 13, 2007 18:22

470 • Chapter 12 / Electrical Properties

Temperature (°C)

Temperature (°F)

Electrical resistivity (10

–8

Ω

• m)

–250 –200 –150 –100 –50 0

d

i

t

Cu + 3.32 at% Ni

Cu + 2.16 at% Ni

Deformed

"Pure" copper

Cu + 1.12 at% Ni

(^0) +50
1
2
3
4
5
6 –400 –300 –200 –100^0 +100
Figure 12.8 The
electrical resistivity
versus temperature for
copper and three
copper–nickel alloys, one
of which has been
deformed. Thermal,
impurity, and
deformation
contributions to the
resistivity are indicated at
–100◦C. [Adapted from
J. O. Linde,Ann. Physik,
5,219 (1932); and C. A.
Wert and R. M.
Thomson,Physics of
Solids,2nd edition,
McGraw-Hill Book
Company, New York,
1970.]
whereρ 0 andaare constants for each particular metal. This dependence of the
thermal resistivity component on temperature is due to the increase with temperature
in thermal vibrations and other lattice irregularities (e.g., vacancies), which serve as
electron-scattering centers.
Influence of Impurities
For additions of a single impurity that forms a solid solution, the impurity resistivity
ρiis related to the impurity concentrationciin terms of the atom fraction (at%/100)
as follows:
ρi=Aci(1−ci) (12.11)
Impurity resistivity
contribution (for
solid solution)—
dependence on
impurity
concentration (atom
fraction)
whereAis a composition-independent constant that is a function of both the impurity
and host metals. The influence of nickel impurity additions on the room-temperature
resistivity of copper is demonstrated in Figure 12.9, up to 50 wt% Ni; over this
composition range nickel is completely soluble in copper (Figure 10.3a). Again, nickel
atoms in copper act as scattering centers, and increasing the concentration of nickel
in copper results in an enhancement of resistivity.
For a two-phase alloy consisting ofαandβphases, a rule-of-mixtures expression
may be utilized to approximate the resistivity as follows:
ρi=ραVα+ρβVβ (12.12)
Impurity resistivity
contribution (for
two-phase
alloy)—dependence
on volume fractions
and resistivities of
two phases
where theV’s andρ’s represent volume fractions and individual resistivities for the
respective phases.