GTBL042-15 GTBL042-Callister-v2 August 29, 2007 8:52
622 • Chapter 15 / Composites
Figure 15.4 Photomicrograph of a WC–Co
cemented carbide. Light areas are the cobalt
matrix; dark regions, the particles of
tungsten carbide. 100×. (Courtesy of
Carboloy Systems Department, General
Electric Company.)
of 15 to 30 vol% of carbon black. For the carbon black to provide significant rein-
forcement, the particle size must be extremely small, with diameters between 20 and
50 nm; also, the particles must be evenly distributed throughout the rubber and must
form a strong adhesive bond with the rubber matrix. Particle reinforcement using
other materials (e.g., silica) is much less effective because this special interaction
between the rubber molecules and particle surfaces does not exist. Figure 15.5 is an
electron micrograph of a carbon black-reinforced rubber.
Concrete
concrete Concreteis a common large-particle composite in which both matrix and dispersed
phases are ceramic materials. Since the terms “concrete” and “cement” are some-
times incorrectly interchanged, perhaps it is appropriate to make a distinction
Figure 15.5 Electron micrograph showing
the spherical reinforcing carbon black
particles in a synthetic rubber tire tread
compound. The areas resembling water
marks are tiny air pockets in the rubber.
80,000×. (Courtesy of Goodyear Tire &
Rubber Company.)