cation is surrounded by six chloride anions, and each chloride anion is surrounded by
six sodium cations.
- In metallic solids,metal atoms occupying the crystal lattice are held together by metal-
lic bonding. In metallic bonding,the electrons of the atoms are delocalized and are
free to move throughout the entire solid. This explains electrical and thermal conduc-
tivity, as well as many other properties of metals. - In covalent network solids,covalent bonds join atoms together in the crystal lattice,
which is quite large. Graphite, diamond, and silicon dioxide (SiO 2 ) are examples of net-
work solids. The crystal is one giant molecule.
Phase Diagrams
The equilibrium that exists between a liquid and its vapor is just one of several that can exist
between states of matter. A phase diagramis a graph representing the relationship of a sub-
stance’s states of matter to temperature and pressure. The diagram allows us to predict
which state of matter a substance will assume at a certain combination of temperature and
pressure. Figure 12.4 shows a general form of the phase diagram.
170 Step 4. Review the Knowledge You Need to Score High
Unit cell
Figure 12.1 The crystal lattice for a simple cubic unit cell.
Figure 12.2 The three types of unit cell of the cubic lattice.
Simple cubic Body-centered cubic Face-centered cubic