122 2 Quantum Mechanics – I
μ=m 1 / 2 = 0. 5 mp
N 0 /N 1 =(1/3) exp
(
^2 /μr^2 kT
)
=(1/3) exp
(
^2 c^2 /μc^2 r^2 kT
)
=
1
3
exp
[ (
197. 3 × 10 −^15
) 2
0. 5 × 938 ×
(
1. 06 × 10 −^10
) 2
×
(
1. 38 × 10 −^23 / 1. 6 × 10 −^13
)
× 300
]
= 0. 445
2.62ω=
√
k
μ
μ=
mNm 0
mN+m 0
= 7 .466 amu
ω=
(
1550
7. 466 × 1. 67 × 10 −^27
) 1 / 2
= 3. 526 × 1014 s−^1
E=ω=
1. 055 × 10 −^34 × 3. 526 × 1014
1. 6 × 10 −^19
= 0. 2325
λ=
1 , 241
0. 2325
nm= 5 ,337 nm= 5. 34 μm
This wavelength corresponds to Infrared region.
2.63 (i)λ=
c
ν
=
3 × 108
1. 153 × 1011
= 2. 6 × 10 −^3 m= 2 .6mm
It lies in the microwave part of electromagnetic spectrum.
(ii) E(eV)=
1241
λ(nm)
=
1241
2. 6 × 106 (nm)
= 0 .000477 eV
(iii)μ=
mcm 0
mc+m 0
=
12 × 16
12 + 16
= 6. 857 u
(iv) E 1 =
1(1+1)^2
2 μr^2
=
^2
μr^2
E 0 = 0
ΔE=E 1 −E 0 =
^2
μr^2
r=
(
^2 c^2
μc^2 ΔE
) 1 / 2
=
(
197. 32 (MeV−fm)^2
6. 857 × 931. 5 × 477 × 10 −^12
) 1 / 2
= 0. 113 × 10 −^9 m
= 1. 13 A ̊
2.64 EJ=
J(J+1)^2
2 Io
Io=μr^2 =
(
Mp
2
)
r^2