Problems 581
- There are four esters with molecular formula How could they be distinguished by NMR?
- An alkyl halide reacts with an alkoxide ion to form a compound whose NMR spectrum is shown here. Identify the alkyl halide
and the alkoxide ion. (Hint:see Section 11.9.)
10 9 8765 4 3 210
δ (ppm)
frequency
1 H
C 4 H 8 O 2. 1 H
2.6 2.7 2.8 2.9 3 3.5 4 4.5 5 5.5 6 7 8 9 10 11 12 13 14 15 16
380036003400320030002800260024002200 2000 1800 1600 1400 1200 1000 800 600
87654 3210
% Transmittance
4000
2.5 Wavelength (μm)
Wavenumber (cm−^1 )
C 4 H 8 O 2
Offset: 2.0 ppm
d.
δ (ppm)
frequency
