Summary of Reactions 661- Reactions of amines with nitrous acid (Section 16.12)
- Replacement of a diazonium group (Section 16.10)
N Cl−+
N OHCu 2 O + N 2
Cu(NO 3 ) 2 , H 2 ON Cl−+
NH 3 PO (^2) + N 2
H
N Cl−
- N OH
H 3 O + HCl + N 2
∆
N Cl−
N
- BF 3
F
HBF (^4) + N 2
∆
N Cl−
N
- N 2
I
KI
N Cl− N
N
- N 2
C
CuC N
NNCl−
CuCl + N 2
NNBr− Cl
CuBr + N 2
Br
O
N
NaNO 2 , HCl
0 °C
(CH 3 ) 2 N (CH 3 ) 2 N
tertiary amine
NaNO 2 , HCl
0 °C
NH 2 NNCl−
primary amine
NaNO 2 , HCl
0 °C
CH 3 NH CH 3 NN O
secondary amine