Problems and Solutions on Thermodynamics and Statistical Mechanics

(Ann) #1

Solution:
(a) The energy of black body radiation is


E=2//- dnpdnq AW
(2nh)n ehwl2nkT - 1

For the radiation we have p = Aw/c, so


where x = Aw/kT. Hence Q = n + 1.


(b) The Debye Model regards solid as an isotropic continuous medium
with partition function


nN nN

[ i=i 1 j=1


Z(T,V) = exp -AEw;/2kT n[l- exp(-f~wi/kT)]-l


The Holmholtz free energy is

nN
h nN
F=-kTlnZ= -~w;+kT~ln[l-exp(-hw;/kT)].
i=l i= 1
2

When N is very large,


nN
-+ $ lwD wn-'dw ,
i=l

where WD is the Debye frequency. So we have


AWD + (kT)n+i ___ xn-' ln[l- exp(-x)]dx ,
(ftwD)n n2N lXD

n2N
2(n + 1)

F= -


where XD = hwD/kT. Hence


cv=-T(~)mTn, a2 F


i.e., B = n.

Free download pdf