111
0111
0111
0111
0111
0
111
INDEX
absorbance 198
absorption spectrometry 223–224
absorptivity, molar 198
accreditation system 19
accuracy 26–27
acid–base
dissociation 58
titrations 80–84
action
levels 49
lines 50
activity 56
adsorption 122
chromatography 166
aminoalkyl bonded phase 168
amperometry seevoltammetry and
amperometry
analogue-to-digital convertor
(ADC) 148
analysis of variance (ANOVA)
39–40, 51
analyte 1
analytical chemistry
definition 1
purpose 1–2
scope and applications 2
analytical methods 5–8
development and validation 7
analytical problems 3
analytical procedures 3–4
anisotropy, diamagnetic 253–254
anodic stripping voltammetry 101
asymmetry potential 70
atmospheric pressure chemical
ionization (APCI) 302
atomic absorption spectrometry
(AAS) 218
atomic fluorescence spectrometry
(AFS) 218, 221
attenuated total reflectance (ATR)
240
Auger effect 214
auxochromes 224, 229
averages 49band broadening effect 124–126
bandpass 198
base peak 270
bathochromic shift 229
Beer–Lambert absorption law 197
bias 22–23
blank
indicator 23
solution 23
titration 82
blue shift 229
Boltzmann distribution law
196–197bonded phase 116, 123, 159, 161,
168
chromatography (BPC) 167
Bragg equation 216
buffers 75–77
capacity 77
running 177calibration 15–16, 41–48, 130
capillary electrochromatography
(CEC) 177, 186
capillary electrophoresis 171, 183
capillary gel electrophoresis (CGE)
186
capillary isoelectric focusing (CIEF)
186
capillary (open tubular) columns
142
capillary zone electrophoresis
(CZE) 183
carbon-13 NMR spectra 267–268
cellulose, powdered 133
centre of symmetry 236
certificate of analysis 4
certified reference material (CRM)
16
charge-transfer bands 229
chelate complexes 113
chemical ionization (CI) 274
chemical shift 248, 251–255, 261
chemometrics 21
chiral chromatography 123, 170
chromatographic techniques 5,
119–121
chromatography
qualitative analysis 129–130
quantitative analysis 129–130
see alsospecific types of
chromatography
chromogenic reagent 134
chromophores 228
Clark sensor 102
clean-up 7
cluster analysis 53
coefficient of linear expansion 316
coefficient of variation 30, 51
column electrophoresis 182
column and stationary phase
141–145, 158–159
columns, packed 143
complexation 85–87
equilibria 59
titrations 90–92
compleximetric indicators 91
computerized analysis 245
concentration profile 124
conductance 105
monitors 164–165
conductimetry 104–107, 169conductivity 105–106
confidence limits 31, 32, 45, 51
coning and quartering 11
continuous wave (CW) NMR 257
control charts 18, 49–50
correlation coefficient 42–43
coulometric methods 99
counter electrode 98
crystalline membrane electrodes 70
cyanoalkyl bonded phase 168Debye–Hückel theory 57
decision tree 245
decomposition
potential 98
temperature 306
degeneracy 196–197
degrees of freedom 29, 31, 33
densitometer, thin-layer
chromatography 134
derivative thermogravimetry (DTG)
307
deshielding, paramagnetic 255
detection, limit 46
dielectric constant 56
dielectric thermal analysis (DETA
or DEA) 319
differential scanning calorimetry
(DSC) 311–315
differential thermal analysis (DTA)
311–315
diffusion 124–125
diffusion current, limiting 100
dilatometry 316
dipole moment 234
disk electrophoresis 182
distribution ratio 110, 120, 121, 131
Dixon’s Q-test 35
dropping mercury electrode (DME)
101
drying and heating 96
dynamic mechanical analysis
(DMA) 317efficiency and resolution 126–129
electro-osmosis 176
electrochemistry 61–65, 164
electrochromatography see
electrophoresis and
electrochromatography
electrode potentials 63–64
electrodeless discharge lamps 220
electrogravimetry 65, 99
electrolysis 64–65
electrolytes, strong and weak 57
electromagnetic radiation, atomic
energy levels 189, 191–192
electromotive force (emf, E) 62
electron capture detector (ECD) 147