Statistical Physics, Second Revised and Enlarged Edition

(Barry) #1
Summary 95

8.4 Summary


This chapter discusses the properties of an ideal Fermi–Dirac gas.




  1. Quantum statistics rather than MB statistics canbe appropriateforgases athigh
    density, low temperature and light particle mass.




  2. The exclusion principle dominates FD statistics, since the maximum occupation
    number ofa one-particle stateis 1. States arefullor empty.
    3 .AtT=0 there is a sharp Fermi energy, defined so that all lower energystates are
    full, and all higher energy states are empty.




  3. This energycanbe representedbya ‘Fermisurface’ink-space




  4. At higher temperatures, the Fermi surface becomes blurred, with states withinkkkBT
    ofthe surfacehavingintermediate occupation on average.




  5. Manythermodynamic properties of thegas are related to those of the MBgas,
    reduced by a factorkkkBT/εF.




  6. Conduction electronsin metals provide a goodexampleofFD properties, even
    thoughthedensityofstatesis not that ofanidealfreegas.




  7. Liquid helium-3 is (surprisingly) another candidate, for reasons which will be
    exploredfurtherinChapter 14.




  8. Thephasediagram ofhelium-3 shows that thesolid is moredisorderedthan the
    liquid, a demonstration that the lack of flexibility in the FD gas inhibits spin
    disorder.



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