26 MHR • Unit 1 Metabolic Processes
Cellular respiration is an important example
of a redox reaction that takes place in biological
systems. The overall reaction is:
In cellular respiration, high-energy electrons are
removed from food molecules, which oxidizes
them. These high-energy electrons are transferred
to increasingly electronegative atoms, and help the
cell manufacture energy-rich molecules used by
cells to do work.
Hydrolysis and
Condensation Reactions
Macromolecules in living systems are built and
broken down by hydrolysis and condensation
reactions (see Figure 1.17). In condensation(or
dehydration synthesis), the components of a water
molecule are removed to bond two molecules
together. Because the organic molecule formed is
bigger than the two organic molecules that reacted,
condensation is an anabolic process. In the process
of hydrolysis, the components of a water molecule
are added to a molecule to break it into two
molecules. Because the organic molecules
produced are smaller than the organic molecule
that reacted, hydrolysis is a catabolic process. Read
on to see how hydrolysis and condensation work to
break down and build carbohydrates, nucleic acids,
proteins, and lipids.
Making and Breaking
Carbohydrates
Carbohydrates are important macromolecules
because they store energy in all organisms.
Carbohydrates are groupings of C, H, and O atoms,
usually in a 1:2:1ratio. Often, carbohydrates are
represented by the chemical formula (CH 2 O)n,
where nis the number of carbon atoms in the
carbohydrate.
Carbohydrates can be simple, such as the
monomer glucose. Glucose is a hexose (six-carbon)
sugar with seven energy-storing C-H bonds. If
the number of carbon atoms in a carbohydrate
molecule is low (from three to seven), then it is a
monosaccharide. Greek prefixes for the numbers
three through seven are used to name these sugars.
For example a five-carbon sugar is a pentose, and a
six-carbon sugar is a hexose. The glucose, fructose,
and galactose isomers you studied in the previous
section are all hexoses. Glucose is the primary
source of energy used by cells.
Two monosaccharides can bond to form a
disaccharide. For example, two glucose molecules
can join to form the disaccharide maltose, as
shown in Figure 1.18.
Organisms store energy in molecules known as
polysaccharides. Polysaccharide molecules, such as
starch and glycogen, are polymers made up of chains
of linked monosaccharides. The long chains of
glucose molecules, which make up starch, glycogen,
C 6 H 12 O 6 + 6O 2 → 6CO 2 + 6H 2 O + energy
glucose
HO
HO H
HHHO
HO H
HO H
HO H
condensation hydrolysis
HO 2 HO 2
Figure 1.17Condensation
and hydrolysis
++
H
O
C 6 H 12 O 6
CH 2 OH CH 2 OH CH 2 OH CH 2 OH
glucose glucose
HO 2
HO
H
O
C 6 H 12 O 6 C 12 H 22 O 11
O
O
maltose
condensation
synthesis
hydrolysis
water
O
OH
Figure 1.18Maltose is a disaccharide. During condensation synthesis of maltose,
a bond forms between the two glucose molecules and the components of water
are removed. During hydrolysis, the components of water are added, and this
bond is broken.