Biomimetic Modifications of Calcium Orthophosphates
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Ca+^2
CaHCO^3+
CaCl+
CaHPO^4 CaCO^3 CaPO^4 - CaSO^4
CaH(Gly)+^2
Ca(Gly)+01020304050607080specie distribution, %Mg+^2 MgCl+
MgHCO^3 +MgHPO4
MgSO^4
MgCO^3
Mg(Gly)+01020304050607080specie distribution, %c dCa+^2
CaHCO^3 +CaCl+
CaHPO^4 CaCO^3 CaSO^4
CaH2 PO4 +
CaH(Gly)+01020304050607080species distribution, %Mg+2
MgCl+
MgHCO^3+
MgH2 PO4 +
MgHPO^4 MgSO^4
Mg(Gly)+01020304050607080species distribution, %e fFig. 7. Ca and Mg species distribution in initial SBF (a and b); at maturation of *ACP (c and
d); at maturation of **ACP (e and f)
0 5 10 15 60 70 800.020.040.060.080.100.12time, hZn2+/(Zn2+ + Ca2+) molar ratioFig 8. Time dependence of the solid phase Zn2+/(Zn2+ + Ca2+) molar ratio during maturation.