Front Matter

17.2 Lipase- and protease-catalyzed esterification of lipids 367

Table 1.

Lipase-catalyzed glycolipid syntheses in a) organic solvents, ranked for their log

P

values, and b) solvent-free systems.

Lipase

Solvent

Log

P

Lipid reactand

Sugar/Polyol

Reference

Candida antarctica

B

1

2-Methyl-2-butanol

+ 1.30

C

18 : 1

methylester,

Rape seed oil

Fructose

Coulon et al., 1999

Pseudomonas

sp.

n-Hexane,

n-Octane,

n-Dodecane

+ 3.5, +4.5, + 6.6

C

16 : 0

Glucose, Galactose,Fructose, Sorbose,Sucrose, Maltose,Lactose

Tsuzuki et al., 1999

Rhizomucor miehei

1

n-Hexane

+ 3.5

C

12 : 0

,C

16 : 0

,C

18 : 1

Fructose

2 , Glucose

2

Stamatis et al., 1998

Rhizomucor miehei

Supercritical CO

2

C

12 : 0

,C

16 : 0

,C

18 : 1

Fructose

2 , Glucose

2

Stamatis et al., 1998

Rhizomucor miehei

1

C

8:0

Fructose

Guillardeau et al. 1992

Rhizomucor miehei

1

C

18 : 1

Isosorbide, Sorbitol

Mukesh et al., 1993

Candida antarctica

B

1

C

18 : 1

Fructose

Coulon et al., 1995

Rhizomucor miehei

1

C

10 : 0

Sucrose

Kim et al., 1998

1

Immobilized enzymes.

2

Adsorbed to silica gel