Front Matter

17.2 Lipase- and protease-catalyzed esterification of lipids 369

Table 2.

Lipase-catalyzed glycolipid syntheses in the presence of adjuvants.

Lipase

Adjuvant

Log

P

Lipid Reactand

Sugar/Polyol

Reference

Candida antarctica

B

1

Acetone or Dioxane

–0.23–1.10

C

12 : 0

–C

18 : 0

Glucose, Mannose,Galactose, Mannitol,Sorbitol

Cao et al., 1996,Cao et al., 1997

Candida antarctica

B

1

2-Methyl-2-butanol/n

-Hexane

+ 1.3/+ 3.5

C

12 : 0

Sorbitan

Sarney et al., 1997

Candida antarctica

B

1

Dioxane or Tetra-hydrofuran (or mono/diglyme)

–1.10+ 0.49

Vinyl- and methylestersof C

4:0–C22:0

(saturated andunsaturated)

Glucose, Fructose,Sucrose, Ascorbic acid

Aha et al., 1997a; 1997b;1998; Berger et al., 1998

Candida antarctica

B

1

t-Butanol

+ 0.80

Phenylbutyric acid

n-Alkyl-glycosides

Otto et al., 1998a

Candida antarctica

B

1

t-Butanol

+ 0.80

n-Butanol, Cinnamicalcohol

Glucuronic acid

Otto et al., 1998b

Candida antarctica

B

1

t-Butanol

+ 0.80

Arylaliphatic acids,Aliphatic acids (C

8,10

)

Glucose, Alkyl-glucoside Otto et al., 1998c

Candida antarctica

B

1

t-Butanol

+ 0.80

Arylaliphatic acids

Glucose

Otto et al., 2000

Candida antarctica

B

1

Ethyl methyl ketoneAcetone

–0.800.23

C

8:0

,C

16 : 0

,C

18 : 0

Methylesters of C

8:0

,

C

16 : 0

,C

18 : 0

GlucoseGlucose

Yan et al., 1999

1

Immobilized enzymes.