glycoproteins 268
glycosidase 363f, 376f
glycosylation
glycosidase-catalyzed – 376f
Rhizopus delemarlipase 72
gondoic eicosenoic acids 35
GPCseeglycerolphosphatidylcholine
Grignard reaction 138, 151, 157
H
a-helix lid 46
heme domain, monooxygenase 401
hesperidinase 384
heterogeneous catalysis, phospholipase 272
high-temperature gas chromatography (HTGC)
158
Hisgap, microbial lipase 94f
histidines 73
HKD motifs 230f
hollow-fiber bioreactor 266
homogeneous triglycerides 176
homology,Rhizopus delemarlipase 74, 77
HPETE 310
HPLC, silver-ion 153
human milk fat 192
Humicola lanuginosalipase
production 78
structure 86
w/o ME 50
hydrocarpic acids 26
hydrogen peroxide 116
hydrolysis
for lipid enrichment 185, 192
glycerides 3f, 12, 16f, 35, 103, 152, 163
in w/o ME 48, 53
phospholipids 232, 246, 295f
PUFA-rich oils 129f
hydroperoxide lyase pathway (HPL) 332
hydroperoxides 63
conjugated – 338, 351
hydroperoxy eicosatetraenoic acid 310
hydroperoxidase 311ff
hydrophilic–lipophilic balance, surfactants
54
hydrophobized sugars 364, 370f
hydroxy acids 39
hydroxy polyenoic fatty acids 317ff
hydroxylation, fatty acids 394–414
I
immobilization
lipase 5, 85, 116, 136, 160f, 200ff, 364
phospholipase 238, 263–291
inactivation, irreversible – 63
inactive lipase 56
inclusion bodies,Rhizopus delemarlipase 79
incorporation, acyl 196
inhibition
in w/o ME 51
lipase 86
phospholipase 227
interesterification
lipid enrichment 177
oil/fats 3, 23f, 35, 162, 192ff, 268
interfacial activation
lipase 75, 85
phospholipase 226, 235, 265, 275
interfacial areas, w/o MEs 46
interfacial binding sites 226
interfacial tension, encapsulated lipase 56
intermediates, lipase 86
ion-exchange resin 271
ionic interaction, phospholipase 267
isoelectric point,Rhizopus delemarlipase
72
isomer separation, triglycerides 153
isopropylidene glycerol 107J
jasmonic acid 339K
kinetic resolution
fatty acids 23f, 30
lipid enrichment 173
kinetically controlled glycosylation 376
kinetics
interesterification 198ff
phospholipase 233ff
structured lipids 134
w/o ME 49fL
lactone formation 48, 352
lactonic sophorolipids 381
lauryl alcohol 6ff
lecithin
gels 62
phospholipids 264, 284f
surfactants 54
w/o ME 51
lectin 268
leucotrienes
activity 312, 328
lipoxygenase 339
lid, lipase 73, 86
linoleate lipoxy generation 315
linolenic acid (LA)
encapsulation 63
epoxidation 120
occurrence 8
oxygenation 338
structured lipids 129
a-linolenic acid 140