c-linoleic acid (GLA)
enrichment 131f
oxygenation 344f
structured lipids 129, 140
lipase 1–216
adsorption 60
ester–ester exchange 193
free fatty acids 3f
glycolipids 363ff
immobilized 269, 274, 279
inactivation 56
lipid enrichment 129–148, 171–190
process engineering 191
production 71
recovery 4, 58
reusability 203
secondary structure 56
selectivities 3–22, 23–45, 85–99
stability 56
stereoselectivity 85–99
structure 73ff, 86ff
structured lipids 129–148, 149–170
lipid coating 238, 283
lipid oxidation 116–128
lipid transformations 219–262
lipids, structured – 48, 135f, 140f, 149–170, 173,
186, 192
Liposam 155f
liposomes 233, 292f
lipoxin 339, 347, 354
lipoxygenase (LOX) 309–336, 337–359
applications 329f, 339f
catalytic cycle 310f
dioxygenase reaction 310
encapsulation, w/o MEs 63
hydroperoxidase activity 312
leukotriene synthase activity 312
mechanism 310
nomenclature 309, 321, 338
occurrence 309, 338
specificity 313f, 338
Lipozymesee Rhizomucor mieheilipase
liquid–liquid extraction, lipase 58
long-chain fatty acids 149
long-chain polyunsaturated acid (LCPUFA) 6f
see alsoPUFA
LOXseelipoxygenase
lyase 356
lyso-glycerophospholipids 295
lysolecithin 274, 278
lysophosphatic acid (LPA) 297ff
lysophospholipase 221
lysophospholipids 264f, 280, 287
M
MAGseemonoglycerides
MCFAseemedium-chain fatty acids
mammalian lipoxygenase 317, 321
margarine fats 192
mass transfer, interesterification 210
mature lipase,Rhizopus delemar 77f
medium-chain fatty acids (MCFA) 186
membrane bioreactors 59, 208
membranes, artificial – 279
mesoporous phases 269
metal complex interaction, phospholipase 267
metal oxides, carrier materials 269
metal salts, PUFA hydroperoxides 355
methylene-interrrupted pentadienyl system
344ff
micellar concentration, glycolipids 386
micellessee alsomicroemulsions
phospholipids 233, 265
Michaelis–Menten kinetics 198, 204, 235, 272
microaqueous systems 162f
microemulsionssee alsowater-in-oil micro-
emulsions
applications 48f
encapsulated lipase 47
gels 47
glycerophospholipids 296
kinetics 49f
MAG synthesis 15
microenvironmental effects 200
microspheres, phospholipase 267
migrationseeacyl migration
MLM (medium-long-medium chain) type tri-
glycerides
136, 149ff
modeling
specificity 88
stereoselectivity 92
modification, glycolipids 363–393
molar ratio, w/o ME 51
molecular dynamics simulation
lipase 81, 89
molecular structuresseestructures
monitoring, triglycerides 151
monoacylglycerolsseemonoglycerides
monoglycerides (MAG) 13ff
analysis in structured lipids 167
enrichment 39
1(3)-MAG 17f, 107ff
2–MAG 15f
self-epoxidation 121
sulfates 112f
synthesis 100–115, 150ff, 192, 197
monoglycerolsseemonoglycerides
monooxygenase (P450) 394–414
classification 396
nomenclature 396
occurrence 394
properties 394
monopentadecanoin 110