suprastructures, phospholipids 233
surface active properties, sophorolipids 383ff
surface dilution model, phospholipase 235
surfactants
diglycerides 100ff
effect on phospholipase 265, 285
glycolipids 386
monoglycerides 15, 100ff
w/o ME 46, 54ff
T
TAGseetriglycerides
taurocholate 54
tautomerization 162
temperature effects, w/o ME 50
tension, interfacial – 56
tetradecenoic acid 120
tetrahedral intermediates 81, 86
Tetrahymena pyriformisphospholipase 222
Tetrahymena thermophilaphospholipase 222
thermal activation 203
thermodynamic shift, triglycerides 162
Thiele modulus 202, 272
thin-layer chromatography/flame ionization
detection (TLC/FID) 160
Torulopsis see Candida bombicola/apicola
transesterification
lipase-catalyzed– 37, 46, 110, 151, 155, 162,
302ff
phospholipase-catalyzed – 229, 264, 279
transglycosylation 378
transphosphatidylation
phospholipase 237, 246, 284ff
triacylglycerol acylhydrolaseseelipase
triacylglycerol hydrolaseseelipase
triacylglycerolsseetriglycerides
triads 73ff, 86
tricaprylin 151, 155
triglycerides (TAG)
analysis 151ff
enzymatic modification 3f, 12, 35, 85f, 111,
139, 144, 149ff
in w/o ME 48
lipid enrichment 174
self-epoxidation 121
trimethyl silyl ethers 125
trimyristin 56
triolein 15, 29, 165
tripalmitin 144
Trisoperl 269
trivernolin 29
tuna oil 145, 179, 185
turnover numbers, monooxygenase 404
Tween 54
U
ultrafiltration reactor
in interesterification 208
in phospholipid hydrolysis 62
undecenoic acid 120
under-pressure lipoxygeneration 342
unsaturated fatty acidssee alsoPUFA
epoxidation 119f
unsaturated fatty alcohols 123
urease 273
V
VA-Epoxy-Biosynth 269, 276
vegetable oils 146
vegetal lipoxygenase 338
Vernonia galamensislipase 29
very long monosaturated fatty acids (VLCMFA)
35ff
vesicles, multilamellar – 233
vinyl esters
fatty acids 297f
glycerides 105
volumetric productivity, triglycerides 161
W
water activity 3, 15f, 85, 363f
water content 163, 207, 210
water-in-oil microemulsions (w/o MEs) 46–69
Winsor III ME systems 55
winterization, triglycerides 162
X
X-ray crystallography 81
xenobiotic compounds 394
Z
zwitterionic surfactants 54