Science - USA (2022-04-29)

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SCIENCEscience.org 29 APRIL 2022¥VOL 376 ISSUE 6592 537


Fig. 4. Mechanistic insight.(A) Decrease of protodehalogenation observed with phthalimide caused by stabilization of the OAC. For the x-ray structure (50% probability
ellipsoids), hydrogens and tBu/CF3 disorder are omitted for clarity. (B) Slower quenching is tolerated because of the increased OAC concentration. (C) Increasing active
Ni on cycle by activation of low-valent Ni oligomers.


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