ePTFE and Athletic Shoes
0.1 g/cm^3 , with a porosity of 96%. Den-
sity and porosity are linearly related. If
pore size is quite small, less than 1 μm,
parts can have porosities of up to 90%
porosity; larger size pores (1-6 μm) con-
tribute to driving porosity above 95%.
The heat-treated ePTFE web has a
higher permeability than PTFE to gases
and liquids due to its many pores. It can
also be a semi-permeable membrane by
letting the wetting liquids through and
turning away non-wetting fluids. For
example, a gas-saturated membrane in
contact with gas and water will let gas
through and keep water out as long as
the water pressure is below the water
entry pressure. When porosity climbs
above 9%, air permeability soars while
water-entry pressure decreases to a fair-
ly small value. There is a range where
porosity can be selected to balance the
air permeability and water imperme-
ability, which is useful to applications
such as clothing and shoes.
KEEPING FEET DRY
Bob Gore used ePTFE to make fabrics
and fabric assemblies for companies that
make athletic shoes and clothing. For
shoes, ePTFE, which they trademarked
as Gore-Tex, was packaged as booties
that shoe companies would put between
the exterior fabric and an interior liner.
The exterior fabric is usually not water-
proof, but the Gore-Tex membrane was
and would keep the wearer’s foot and lin-
er dry. By staying relatively dry, the liner
lasts longer and is more comfortable.
Gore-Tex could make socks out of
ePTFE, and they would keep feet dry.
Bob Gore discovered how to expand PTFE and create an adjustable membrane that was
waterproof but would let air go through it, the first truly breathable fabric.
34
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