1549380323-Statistical Mechanics Theory and Molecular Simulation

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The ideal fermion gas 419

Pλ^3
gkT

=


∑∞


l=1

(−1)l+1ζl
l^5 /^2

ρλ^3
g

=


∑∞


l=1

(−1)l+1ζl
l^3 /^2

, (11.5.7)


whereρ=〈N〉/V is the number density. Although we cannot solve these equations
to obtain a closed form for the equation of state, two interesting limits can be worked
out to a very good approximation, which we examine next.


11.5.1 The high-temperature, low-density limit


Solving forζas a function of〈N〉is equivalent to solving forζas a function ofρ.
Hence, in the low-density limit, we can take an ansatz forζ=ζ(ρ) in the form of a
power series:
ζ(ρ) =a 1 ρ+a 2 ρ^2 +a 3 ρ^3 +···. (11.5.8)


How rapidly this series converges depends on how low the density actually is. Writing
out the first few terms in the pressure and density equations, we have


Pλ^3
gkT

=ζ−

ζ^2
25 /^2

+


ζ^3
35 /^2


ζ^4
45 /^2

+···


ρλ^3
g

=ζ−

ζ^2
23 /^2

+


ζ^3
33 /^2


ζ^4
43 /^2

+···. (11.5.9)


Substituting eqn. (11.5.8) into eqns. (11.5.9) gives


ρλ^3
g

= (a 1 ρ+a 2 ρ^2 +a 3 ρ^3 +···)−

1


23 /^2


(a 1 ρ+a 2 ρ^2 +a 3 ρ^3 +···)^2

+


1


33 /^2


(a 1 ρ+a 2 ρ^2 +a 3 ρ^3 +···)^3 +···. (11.5.10)

Eqn. (11.5.10) can be solved perturbatively, equating like powers ofρon both sides.
For example, if we work only to first order inρ, then we have


ρλ^3
g

=a 1 ρ ⇒ a 1 =

λ^3
g

⇒ζ≈

λ^3 ρ
g

. (11.5.11)


When eqn. (11.5.11) is substituted into eqn. (11.5.9) for the pressure and only terms
first order in the density are kept, we obtain


Pλ^3
gkT

=


ρλ^3
g


P


kT

=ρ=

〈N〉


V


, (11.5.12)


which is just the classical ideal gas equation. If we now go out to second order inρ,
eqn. (11.5.9) gives

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