1549380323-Statistical Mechanics Theory and Molecular Simulation

(jair2018) #1

630 Critical phenomena


an unsolved problem. Should an exact solution emerge, the exponents for thed= 3,
n= 1 universality class would be known.
Graph-theoretic approach: The second approach is a combinatorial one that leads
directly to the partition of the two-dimensional Ising model in the zero-field limit. We
begin by introducing the shorthand notationK=βJ, and again we assume periodic
boundary conditions. The partition function in the zero-field limit canbe written as


Q(N,T) =


σ 1 , 1 =± 1


σ 2 , 1 =± 1

···



σn, 1 =± 1


σ 1 , 2 =± 1


σ 2 , 2 =± 1

···



σn, 2 =± 1

··· (16.7.14)


×



σ 1 ,n=± 1


σ 2 ,n=± 1

···



σn,n=± 1

exp




K


∑n

i,j=1

[σi,jσi+1,j+σi,jσi,j+1]




.


The combinatorial approach starts with an identity derived from the fact that the
product of spinsσi,jσi′,j′ =±1 so that exp[Kσi,jσi′,j′] = exp[±K] = cosh(K)±
sinh(K). From these relations, it follows that


exp [Kσi,jσi′,j′] = cosh(K) +σi,jσi′,j′sinh(K)

= cosh(K) [1 +σi,jσi′,j′tanh(K)]

= cosh(K) [1 +vσi,jσi′,j′], (16.7.15)

wherev= tanh(K). Converting exponentiated sums into products, the partition func-
tion can be written as


Q(N,T) =



{σ}=± 1

exp




K



i,j

[σi,jσi+1,j+σi,jσi,j+1]




=



{σ}=± 1

exp




K



i,j

σi,jσi+1,j




exp




K



i,j

σi,jσi,j+1




=



{σ}=± 1




i,j

eKσi,jσi+1,j






i,j

eKσi,jσi,j+1



=



{σ}=± 1




i,j

cosh(K) (1 +vσi,jσi+1,j)






i,j

cosh(K) (1 +vσi,jσi,j+1)



= [cosh(K)]ν


{σ}=± 1


i,j

[1 +vσi,jσi+1,j] [1 +vσi,jσi,j+1], (16.7.16)

whereνis the total number of nearest neighbors on the two-dimensional lattice and
the notation



{σ}=± 1 indicates that all spins are summed over.
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