1549380323-Statistical Mechanics Theory and Molecular Simulation

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632 Critical phenomena


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(2,1) (2,2)


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Fig. 16.11 Graphical representation of eqn. (16.7.17).

r= 6 and whenr= 8. Oncen(r) is known, the partition function can be shown to
take the following form:


Q(N,T) = 2N[cosh(K)]ν


r

n(r)vr. (16.7.18)

We conclude this brief discussion by illustrating how eqn. (16.7.18) canbe applied
to the one-dimensional Ising model on a periodic lattice. The partition function was
given by eqn. (16.6.10), which forh= 0 becomes


Q(N,T) = 2N


[


coshN(K) + sinhN(K)

]


. (16.7.19)


We now show that the graph-theoretic approach can be used to derive eqn. (16.7.19).
First, note that on a one-dimensional periodic lattice, only two graphs contribute: the
graph withr= 0 and the graph withr=N, which is the only closed graph that can
be drawn forr >0,i.e., one that involves each vertex in two edges. Thus,n(N) = 1,

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