A PARADIGM SHIFT 229
a French PhD student, Louis de
Broglie, whose suggestion led the
quantum revolution into a dramatic
new phase. Not only did de Broglie
demonstrate with a simple
equation how, in the subatomic
world, particles could equally be
waves, he also showed how any
object, of whatever mass, could
behave as a wave to some extent.
In other words, if light waves had
particle-like properties, then particles
of matter—such as electrons—
must have wavelike properties.
Planck had calculated the
energy of a light photon with the
simple equation E = hv, where E
is the energy of the electromagnetic
quanta, v is the wavelength of
the radiation involved, and h is
a constant, today known as
the Planck constant. De Broglie
showed that a light photon also has
momentum, something normally
only associated with particles
with mass and given by multiplying
the particle’s mass with its speed.
De Broglie showed that a light
photon had a momentum of
h divided by its wavelength.
However, since he was dealing
with particles whose energy and
mass might be affected by motion
at speeds close to that of light, de
Broglie incorporated the Lorentz
factor (p.219) into his equation.
This produced a more sophisticated
version that took into account
the effects of relativity.
De Broglie’s idea was radical
and daring, but it soon had
influential supporters, including
Einstein. The hypothesis was
Two seemingly incompatible
conceptions can each represent
an aspect of the truth.
Louis de Broglie
See also: Thomas Young 110–11 ■ Albert Einstein 214–21 ■ Werner Heisenberg 234–35 ■ Paul Dirac 246–47
Richard Feynman 272–73 ■ Hugh Everett III 284–85
If you fire electrons one-by-one
through two slits onto a screen, they
will build up an interference pattern
on the screen.
This means that they are
behaving like waves.
A wave function provides a way
of calculating the probability of
detecting an electron at a particular
point in space-time.
Particles have
wavelike properties.
also relatively easy to test. By
1927, scientists in two separate
laboratories had conducted
experiments to show that electrons
diffracted and interfered with each
other in exactly the same way as
photons of light. De Broglie’s
hypothesis was proved.
Growing significance
In the meantime, a number of
theoretical physicists were
sufficiently intrigued by de Broglie’s
hypothesis to investigate it further.
In particular, they wanted to know
how the properties of such matter
waves could give rise to the pattern
of specific energy levels among the
electron orbitals of the hydrogen
atom proposed by Bohr’s model of
the atom. De Broglie himself had
suggested that the pattern arose
because the circumference of each
orbital must accommodate a whole
number of wavelengths of the
matter wave. Since the electron’s
energy level depends on its
distance from the atom’s positively
charged nucleus, this meant that ❯❯