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234 CHAPTER14. THEADDITIONOFANGULARMOMENTUM


Then,usingthefactthatfortheHydrogenatomgroundstate


|ψ(r=0)|^2 =

1


πa^30

(14.83)


withBohrradiusa 0 =h ̄^2 /me^2 ,weget


∆E=


4 gp ̄h^4
3 mpm^2 ec^2 a^40

{ 1
4 (triplet)
−^34 (singlet)

(14.84)


Itisthenpossiblefortheelectron-protonsystemtomakeatransitionfromthe
higherenergytripletstate,tothelowerenergysingletstate,emittingaphoton,whose
energyisthedifferenceinenergiesbetweenthetriplet/singletstates. Accordingto
DeBroglierelation,thefrequencyofthisemittedphotonwillbe


f =

∆Etriplet−∆Esinglet
h

=

4 gp ̄h^4
3 mpm^2 ec^2 a^4 h
= 1420 MHz (14.85)

withacorrespondingwavelengthof 21 cm.
Atomichydrogenisthe mostcommonelementfoundininterstellar space, and
transitionsbackandforthbetweenthetripletandsingletstates(separatedbyonly
about 6 millionthsofanelectronvolt),occurveryeasily.Forthatreason,the 21 cm
spectrallineduetotransitionsbetweenthehydrogentripletandsingletstates,isone
ofthemostdominantfeaturesoftheinterstellarradiospectrum.

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