QMGreensite_merged

(bbancia) #1

260 CHAPTER16. LIVEWIRESANDDEADSTARS


Accordingto(16.31),


R=

(
2 mL^2
̄h^2 π^2

EF


) 1 / 2
(16.34)

sothenumberofelectrons,intermsofEF,becomes


N=


π
3

L^3


( 2 mE
F
̄h^2 π^2

) 3 / 2
(16.35)

SolvingfortheFermienergy,weget


EF=


̄h^2 π^2
2 m

( 3 N


πL^3

) 2 / 3
(16.36)

Butthenumberdensityofelectrons,ne,inthesolidisjust


ne=

N


L^3


(16.37)


Therefore, we find that the Fermienergy just depends on the electronmass and
density(andnotonthesizeofthebox)


EF=


̄h^2 π^2
2 m

( 3


π

ne

) 2 / 3
(16.38)

Next,approximatethesumoverallstateswithenergieslessthanEFbyanintegral

ET =


n 1


n 2


n 3

2 En 1 n 2 n 3



"n·"n≤R^2

d^3 n 2 En 1 n 2 n 3

=


h ̄^2 π^2
mL^2

1


8



d^3 n%n·%n

=


̄h^2 π^2
8 mL^2

4 π

∫R

0

dnn^4

=


̄h^2 π^3
10 mL^2

R^5 (16.39)


wherethefactorof 1 / 8 infrontoftheintegralcomes,again,becausethesitesliein
theoctantofthespherewithpositiveintegercoordinates.Nextfrom(16.33)


R=


( 3 N


π

) 1 / 3
(16.40)

UsingL=V^1 /^3 ,whereV isthevolumeofthesolid,wegetfinally


ET=


̄h^2 π^3
10 m

(
3 N
π

) 5 / 3
V−^2 /^3 (16.41)
Free download pdf