Cracking the SAT Chemistry Subject Test

(Marvins-Underground-K-12) #1

ACIDS AND BASES


Over the years, several different definitions for acids and bases have been
introduced.


For example:


Arrhenius: Acids    produce H

+   in  aqueous solution.
Bases produce OH− in aqueous solution.

Lewis: Acids    are electron    pair    acceptors   in  solution.Bases  are electron    pair    donors  in  solution.

Brønsted-Lowry:Acids    are proton  donors; bases   are proton  acceptors.

The Brønsted-Lowry definition is the one that’s most widely used today,
although it is commonplace for chemists to flip between the Brønsted-Lowry
and Arrhenius definitions.


Brønsted-Lowry Acids and Bases


The most important thing to remember about the Brønsted-Lowry definition of
acids and bases is that acids are proton donors and bases are proton acceptors.
The term proton is used to mean H+(aq), and H+(aq) reacts with water to form
the hydronium ion, H 3 O+(aq).


    Acid    Dissociation Reaction   of  a   Base
HA(aq) → H+(aq) + A−(aq ) A−(aq) + H+(aq) → HA(aq)
or or
HA(aq) + H 2 O(l) → H 3 O+(aq) + A
−(aq )

    A−(aq)  +   H 2 O(l)    →   HA(aq)  +   OH
−(aq)
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