5 Steps to a 5 AP Chemistry 2019

(Marvins-Underground-K-12) #1
352 ❯ STEP 5. Build Your Test-Taking Confidence

HNN N N

H N

H H

H

NH

Diazene Triazene

N

Tetrazene

N

H

N

H

H


  1. Ammonia is the best-known nitrogen-hydrogen
    compound; however, there are a number of other
    nitrogen-hydrogen compounds, three of which
    are in the above diagram. Which of these has the
    longest average N-N bond length?
    (A) N 2 H 2
    (B) N 3 H 3
    (C) N 4 H 4
    (D) They are all the same.

  2. The above equilibrium was established in a 1.00 L
    container at a certain temperature. Once the system
    came to equilibrium, it was found that the following
    amounts of materials were present in the container:
    (NH 4 ) 2 CO 3 = 8.00 moles, NH 3 = 4.00 moles,
    CO 2 = 2.00 moles, and H 2 O = 2.00 moles.
    Determine the value of Kc at this temperature.
    (A) 8.00
    (B) 64.0
    (C) 4.00
    (D) 32.0

  3. A solution of a weak base is titrated with a solu-
    tion of a standard strong acid. The progress of
    the titration is followed with a pH meter. Which
    of the following observations would occur?
    (A) Initially, the pH slowly decreases, then
    there is a rapid decrease to give a pH below
    7 at the equivalence point.
    (B) The pH of the solution gradually decreases
    throughout the experiment, and the pH at
    the equivalence point is below 7.
    (C) Initially, the pH slowly decreases, then
    there is a rapid decrease to give a pH equal
    to 7 at the equivalence point.
    (D) Initially, the pH quickly decreases, then there
    is a gradual decrease to the equivalence point
    where the pOH equals the pKb of the base.
    51. A student mixes 100.0 mL of a 0.10 M hydroflu-
    oric acid, HF, solution with 50.0 mL of a 0.10 M
    potassium hydroxide, KOH, solution. The Ka
    for hydrofluoric acid is 6.8 × 10 -^4. Which of the
    diagrams below best represents the species, other
    than H 2 O, in the solution after the acid reacts
    with the base?


(A)

K+

F K+





F–

(B)


K+ K+

OH– F–

(C)


K+ H F

F H+





F–

(D)


H+

K+

F–

F–

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